Measurement of unsaturated hydraulic conductivity and chemical transport in Yucca Mountain Tuff: Milestone Report 3044-WBS1.2.3.4.1.4.1

Hydraulic conductivities, K, were experimentally determined as a function of volumetric water content, θ, in tuff from the Yucca Mountain site. In addition, the retardation factor, Rf, in Yucca Mountain tuff with respect to selenium, as the selenite species, was measured under unsaturated conditions. These data were used to determine the feasibility of applying a new unsaturated flow technology (UFA) to further hydrologic studies at Yucca Mountain. The UFA directly measures K(θ) rapidly in Yucca Mountain tuff and is shown to agree well with traditional methods. Hysteresis does not appear important during this testing. Hydraulic steady-state is achieved fastest during desaturation from a saturated state. Imbibition into dry tuff requires a long time for steady-state to occur because of slow filling of the diffusion porosity which can take a few weeks. The existing UFA is a prototype, and a new design of the next generation UFA is completed that eliminates some of the earlier problems. These preliminary investigations demonstrates that the UFA is a useful investigate technique that should be used to compliment existing techniques for hydrogeochemical characterization at Yucca Mountain and other arid sites