Published 1986
| Version v1
Book
A neutron powder diffraction investigation of deuterated Pd15P2
- 1. Uppsala Univ. (Sweden). Dept. of Inorganic Chemistry
- 2. Vermont Univ., Burlington (USA). Dept. of Chemistry
Description
Crystal structure refinements of pure and deuterated Pd15P2 have been performed using Rietveld-type profile refinement techniques on neutron powder diffraction intensities. The positions and the degree of occupancy for the dissolved deuterium atoms were determined at 296 K and 500 kPa deuterium pressure. The deuterium atoms were found to occupy distorted tetrahedral interstices between the palladium atoms to an extent corresponding to the formula Pd15P2D0.46. (orig.)
Abstract (German)
Die Kristallstrukturen von reinem und deuteriertem Pd15P2 wurden mittels Neutronenbeugungsaufnahmen von Pulverpraeparaten und Intensitaetsprofilanalyse nach Rietveld ermittelt. Die Atomlagen und der Besetzungsgrad der geloesten Deuteriumatome wurden bei 296 K und 500 kPa Deuteriumdruck bestimmt. Die Deuteriumatome sind in verzerrten tetraedrischen Hohlraeumen zwischen den Palladiumatomen eingelagert. Der Besetzungsgrad entspricht der Formel Pd15P2D0.46. (orig.)Additional details
Publishing Information
- Publisher
- Oldenbourg.
- Imprint Place
- Muenchen (Germany, F.R.)
- ISBN
- 3-486-68270-9
- Imprint Title
- Hydrogen in metals
- Imprint Pagination
- 946 p.
- Journal Page Range
- p. 297-303.
Conference
- Title
- International symposium on hydrogen in metals.
- Dates
- 26-29 Mar 1985.
- Place
- Belfast (UK).
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 19054532
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Conference, Numerical Data
- Descriptors DEI
- CRYSTAL STRUCTURE; DEUTERIUM COMPOUNDS; EXPERIMENTAL DATA; NEUTRON DIFFRACTION; PALLADIUM COMPOUNDS; PHOSPHIDES; POWDERS
- Descriptors DEC
- COHERENT SCATTERING; DATA; DIFFRACTION; HYDROGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; PHOSPHORUS COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- Reprinted from Z. Phys. Chem., Neue Folge (1985) v. 145 p. 43-49.