Published October 27, 2004 | Version v1
Journal article

Colloidal cluster phases, gelation and nuclear matter

  • 1. Polymer Materials and Engineering, Faculty of Applied Sciences, Delft University of Technology, Julianalaan 136, 2628 BL Delft(Netherlands)
  • 2. van' t Hoff Laboratory for Physical and Colloid Chemistry, Debye Research Institute, Utrecht University, Padualaan 8, 3584 CH Utrecht (Netherlands)

Description

The combination of short-range attractions and long-range repulsions can lead to interesting clustering phenomena. In particular there are strong indications that the colloidal cluster phase is in fact a manifestation of such a competition. Here we compute the stability boundary of the cluster phase by invoking counter-ion condensation. It is found that a condensation catastrophe leading to an infinite cluster sets in if the level of charge on the colloid is too low. The same ingredients leading to the cluster phase are found in nuclear physics: strong short-range attractions due to nuclear force and weak long-range Coulomb repulsions. We will show explicitly here the equivalence of a semi-empirical mass formula for the binding energy of the nucleus and the free energy of a cluster in a colloidal cluster phase. This identification enables an exploitation of theoretical results from nuclear physics to the colloidal domain and, perhaps, the construction of a colloidal system mimicking various aspects of nuclear matter

Availability note (English)

Available online at http://stacks.iop.org/0953-8984/16/S4877/cm4_42_006.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/

Additional details

Publishing Information

Journal Title
Journal of Physics. Condensed Matter
Journal Volume
16
Journal Issue
42
Journal Page Range
p. S4877-S4886
ISSN
0953-8984
CODEN
JCOMEL

Conference

Title
Workshop on structural arrest transitions in colloidal systems with short-range attractions
Dates
17-20 Dec 2003
Place
Messina (Italy)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
36033858
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S73: NUCLEAR PHYSICS AND RADIATION PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BINDING ENERGY; COLLOIDS; COULOMB FIELD; FREE ENERGY; GELATION; INTERACTION RANGE; MASS FORMULAE; NUCLEAR FORCES; NUCLEAR MATTER; NUCLEI
Descriptors DEC
DISPERSIONS; DISTANCE; ELECTRIC FIELDS; ENERGY; MATTER; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES

Optional Information

Contract/Grant/Project number
Project MRTN-CT-2003-504712