Published June 15, 1990
| Version v1
Journal article
Crystal chemistry of cyclo-hexaphosphates. Pt. 9
Creators
- 1. Centre National de la Recherche Scientifique, 38 - Grenoble (France). Lab. de Cristallographie
Description
Mn2(NH4)4(P6O18)(C2O4).6H2O, Mr=851.966, triclinic, Panti 1, a=9.747 (3), b=9.751 (3), c=7.689 (3) A, α=99.92 (5), β=105.88 (5), γ=100.08 (5)deg, V=673.1 A3, Z=1, Dx=2.101 Mg m-3, λ(Mo Kα)=0.7107 A, μ=1.465 mm-1, F(000)=432, T=294 K, final R=0.030 for 2577 reflections. The atomic arrangement is built up by infinite ribbons of P6O18 ring anions and MnO6 octahedra spreading parallel to the b axis. These ribbons are themselves interconnected by the oxalic groups located between two MnO6 octahedra belonging to two different ribbons. The hydrogen-bond scheme is described. (orig.)
Additional details
Additional titles
- Subtitle (English)
- Structure of tetraammonium dimanganese cyclo-hexaphosphate oxalate hexahydrate
Publishing Information
- Journal Title
- Acta Crystallographica. Section C: Crystal Structure Communications
- Journal Volume
- 46
- Journal Issue
- 6
- Series
- Acta Crystallogr., Sect. C Cryst. Struct. Comm.
- Journal Page Range
- 965-968
- ISSN
- 0108-2701
- CODEN
- ACSCE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 22005898
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- AMMONIUM COMPOUNDS; CRYSTAL STRUCTURE; EXPERIMENTAL DATA; HYDRATES; LATTICE PARAMETERS; MANGANESE COMPOUNDS; MEDIUM TEMPERATURE; OXALATES; PHOSPHATES; TRICLINIC LATTICES; X-RAY DIFFRACTION
- Descriptors DEC
- CARBOXYLIC ACID SALTS; COHERENT SCATTERING; CRYSTAL LATTICES; DATA; DIFFRACTION; INFORMATION; NUMERICAL DATA; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS