Published September 1987
| Version v1
Journal article
Preparation and properties of molybdenum oxoiodides
Description
Molybdenum oxoiodides of MoO2I and Mo4O11I composition are prepared in the process of molybdenum triiodide oxydation.MoO2I is the product of MoI3 oxydation during heating in the air up to 475 deg K, while Mo4O11I, up to 590 deg K. Both iodides are crystallized in a monoclinic crystal system with parameters: a=15.88, b=3.58, c=8.33A, β=99.7 deg (MoO2I) and a=15.77, b=3.651, c=7.6 A, β=97 deg (Mo4O11I). MoO2I and Mo4O11I are stable in the air but being heated in vacuum in the 473-873 deg K decompose with iodide formation
Additional details
Additional titles
- Original title (Russian)
- Получение и свойства оксоиодидов молибдена
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Neorg. Mater.
- Journal Volume
- 23
- Journal Issue
- 9
- Series
- Izv. Akad. Nauk SSSR, Neorg. Mater.
- Journal Page Range
- 1550-1553
- ISSN
- 0002-337X
- CODEN
- IVNMA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 19071272
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CRYSTAL LATTICES; HIGH TEMPERATURE; INFRARED SPECTRA; LATTICE PARAMETERS; MOLYBDENUM COMPOUNDS; OXYIODIDES; TEMPERATURE DEPENDENCE
- Descriptors DEC
- CRYSTAL STRUCTURE; HALOGEN COMPOUNDS; IODINE COMPOUNDS; OXYGEN COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS