Temperature dependent dielectric function and reflectivity spectra of nonpolar wurtzite AlN

Exciton resonances are observed in the dielectric functions of wurtzite AlN by spectroscopic ellipsometry for the electric field vector parallel and perpendicular to the optical axis. The temperature dependence of these excitons is analyzed in detail. From the dielectric functions, reflectivity spectra are calculated and compared to experimentally obtained reflectivity, perfect agreement is found. The relative oscillator strengths of excitons showing different symmetries are discussed yielding an unambiguous assignment of free excitons formed by holes from the highest valence band. As a consequence, a negative exciton spin-exchange coupling constant of j = − 4 meV is derived. - Highlights: • Anisotropic dielectric function of wurtzite AlN obtained as a function of temperature • Reflectivity measurements performed as a function of temperature • Comparison of both types of spectra yields perfect agreement • In-depth analysis of resonance energies yields an assignment of free exciton symmetry