Published May 1985 | Version v1
Journal article

Study of phase transformations in the series of polyphosphates of rare earths Ln(POΛ3)Λ3 by the method of combination light scattering

  • 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii

Description

Using the method of high-temperature spectroscopy of combination light scattering, temperature boundaries of existence of three structural types - 1, 2, and C polyphosphates of rare earths are determined, and congruent character of Ln(POΛ3)Λ3 melting is established. Interrelaion between the structure of Ln(POΛ3)Λ3 in the melt, glass-like and crystal states, and its effect on the sequence of crystal phase separation, when annealing glasses of the composition LnΛ2OΛ3x3PΛ2OΛ5, has been detected. By means of glass crystallization La(POΛ3)Λ3 in the structural state C has been prepared for the first time

Additional details

Additional titles

Original title (Russian)
Изучение фазовых превращений в ряду полифосфатов редкоземельных металлов Лн(POΛ3)Λ3 методом комбинационного рассеяния света

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Neorg. Mater.
Journal Volume
21
Journal Issue
5
Series
Izv. Akad. Nauk SSSR, Neorg. Mater.
Journal Page Range
712-720
ISSN
0002-337X
CODEN
IVNMA

Optional Information

Notes
For English translation see the journal Inorganic Materials (USA).