Published May 21, 1975
| Version v1
Journal article
On applicability of the diffusion-recombination model for low-temperature radiolysis of solid polar solutions
Creators
- 1. Gosudarstvennyj Komitet po Ispol'zovaniyu Atomnoj Ehnergii SSSR, Moscow. Inst. Teoreticheskoj i Ehksperimental'noj Fiziki
- 2. AN SSSR, Moscow. Inst. Fizicheskoj Khimii
Description
The diffusion-recombination model was employed for describing the mechanism of a low-temperature radiolysis of the solid polar solutions, in particular of the aqueous alkali and methanol solutions. In such solutions an addition of electron acceptors increases the yield of separate ion pairs with respect to the pure matrices. Experimental dependence of these yields versus acceptor concentration was studied. The close total yields of the methanol and alkaline glass decomposition at 77 deg K and room temperature show a community of the primary processes occuring in tracks at the low and high temperature
Additional details
Additional titles
- Original title (Russian)
- О применимости диффузионно-рекомбинационной модели к низкотемпературному радиолизу твердых полярных растворов
Publishing Information
- Journal Title
- Dokl. Akad. Nauk SSSR
- Journal Volume
- 222
- Journal Issue
- 3
- Series
- Dokl. Akad. Nauk SSSR.
- Journal Page Range
- 637-640
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 9407312
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S36: MATERIALS SCIENCE;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; DECOMPOSITION; DIFFUSION; ELECTRONS; LOW TEMPERATURE; METHANOL; RADIOLYSIS; RECOMBINATION; SODIUM HYDROXIDES; SOLID SOLUTIONS
- Descriptors DEC
- ALCOHOLS; ALKALI METAL COMPOUNDS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DISPERSIONS; ELEMENTARY PARTICLES; FERMIONS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; HYDROXIDES; HYDROXY COMPOUNDS; KINETICS; LEPTONS; MIXTURES; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; RADIATION EFFECTS; REACTION KINETICS; SODIUM COMPOUNDS; SOLUTIONS
Optional Information
- Notes
- 15 refs.