Published December 2019
| Version v1
Journal article
A New Coordination Polymer Based on Citric Acid Containing 1D [Ag]∞ Chain with Strong Ag–Ag Bonding Interaction
Description
A new polynuclear silver complex Ag6(W2O5)(Cid)2 based on citric acid is obtained by hydrothermal method and studied by single crystal X-ray diffraction compound The compound crystallizes in triclinic space group P, Z = 1. The structure solution is complicated by two component non-merohedral twinning. The structure feature is a 3D framework containing 1D infinite [Ag]∞ chains. Ag atoms are connected by metal–metal bonding interaction with the Ag–Ag distances of 2.849(3)–3.218(2) Å.
Additional details
Identifiers
Publishing Information
- Journal Title
- Crystallography Reports
- Journal Volume
- 64
- Journal Issue
- 7
- Journal Page Range
- p. 1019-1022
- ISSN
- 1063-7745
- CODEN
- CYSTE3
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 55060812
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BOND LENGTHS; BONDING; CHEMICAL BONDS; CITRIC ACID; HYDROTHERMAL SYNTHESIS; INTERACTIONS; MONOCLINIC LATTICES; MONOCRYSTALS; POLYMERIZATION; POLYMERS; SILVER; SILVER COMPLEXES; SOLUTIONS; SPACE GROUPS; TWINNING; X-RAY DIFFRACTION
- Descriptors DEC
- CARBOXYLIC ACIDS; CHEMICAL REACTIONS; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; DIMENSIONS; DISPERSIONS; ELEMENTS; FABRICATION; HOMOGENEOUS MIXTURES; HYDROXY ACIDS; JOINING; LENGTH; METALS; MIXTURES; ORGANIC ACIDS; ORGANIC COMPOUNDS; SCATTERING; SYMMETRY GROUPS; SYNTHESIS; THREE-DIMENSIONAL LATTICES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2019 © Pleiades Publishing, Inc. 2019