Published June 1991 | Version v1
Journal article Metadata-only

Structural and spectral manifestation of anion-cation interaction in salts of mixed P-W-H heteropolyacids. Crystal structure of Cs5[PCo(H2O)W11O39]·3H2O

Creators

  • 1. AN SSSR, Novosibirsk (USSR). Inst. Kataliza
  • 2. AN SSSR, Novosibirsk (USSR). Inst. Neorganicheskoj Khimii

Description

X-ray diffraction study of Cs5[PCo(H2O)W11O39]·3H2O (1) heteropolycompound (HPC) tetragonal crystals, sp.gr.P42/ncm, a=b=20.810(7), c=10.397(2) A, Z=4, was carried out. The structure contains the Keggin-type heteropolyanion (HPA). Besides salt 1 HPC of the same anion with tetramethyl-(2) and tetrabutylammonium (3) were prepared. Analysis of the Raman and IR spectra of compounds 1-3 shows that the influence of cation nature on position and relative intensities of bands in the spectra is commensurable and sometimes it exceeds the similar influence as a result of HPA composition change

Additional details

Additional titles

Original title (Russian)

Структурные и спектральные проявления анион-катионного взаимодействия в солях смешанных P-W-X гетерополикислот. Кристаллическая структура Cs

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
32
Journal Issue
4
Series
Zh. Strukt. Khim.
Journal Page Range
102-110
ISSN
0136-7463
CODEN
ZSTKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
23041601
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CESIUM COMPOUNDS; COBALT COMPOUNDS; HETEROPOLYANIONS; HYDRATES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; RAMAN SPECTRA; SPACE GROUPS; TETRAGONAL LATTICES
Descriptors DEC
ALKALI METAL COMPOUNDS; ANIONS; CHARGED PARTICLES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; IONS; SPECTRA; SYMMETRY GROUPS; TRANSITION ELEMENT COMPOUNDS