Investigation on boron carbide oxidation for nuclear reactor safety: Experiments in highly oxidising conditions

The oxidation kinetics of boron carbide pellets were investigated in steam/argon mixtures in the temperature range 1200-1800 deg. C for steam partial pressures between 0.2 and 0.8 bar and total flows (steam + argon) between 2.5 and 10 g/min resulting in gas velocities from 1.01 to 5.34 m/s. A kinetic model for boron carbide pellet oxidation depending on temperature, steam partial pressure and flow velocity is obtained. The activation energy of the oxidation process was determined to be 163 ± 8 kJ/mol. The strong influence of temperature and steam partial pressure on the boron carbide oxidation kinetics is confirmed. The obtained data suggest the coexistence of two kinetic regimes, one at 1200 deg. C and the other at 1400-1800 deg. C, with different dependence on steam partial pressure