Published September 7, 2015 | Version v1
Journal article Metadata-only

Generation of polyyne and methylpolyyne molecules from toluene by intense femtosecond laser pulse irradiation

Creators

  • 1. Department of Physics, University of Waterloo, 200 University Ave. W, Waterloo, Ontario, N2L 3G1 (Canada)
  • 2. Department of Chemistry, Kinki University, Kowakae 3-4-1, Higashi-Osaka 577-8502 (Japan)
  • 3. Department of Chemistry, Tokyo Metropolitan University, Minami-Osawa 1-1, Tokyo 192-0397 (Japan)

Description

Hydrogen-capped and methyl-capped carbon chains (polyynes) have been generated by intense femtosecond laser irradiation of pure liquid toluene. UV-Vis and Raman spectroscopy were used to confirm the presence of polyynes in the irradiated samples, and high performance liquid chromatography (HPLC) was used to separate polyynes up to C18 H2 and HC13 CH3. (paper)

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/635/11/112125

Additional details

Identifiers

DOI
10.1088/1742-6596/635/11/112125;

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
635
Journal Issue
11
Journal Page Range
[1 p.]
ISSN
1742-6596

Conference

Title
29. international conference on photonic, electronic, and atomic collisions
Acronym
ICPEAC2015
Dates
22-28 Jul 2015
Place
Toledo (Spain)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
47101875
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
CARBON; HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY; HYDROGEN; LASER RADIATION; LIQUIDS; MOLECULES; PULSED IRRADIATION; RAMAN SPECTROSCOPY; TOLUENE; ULTRAVIOLET SPECTRA; VISIBLE SPECTRA
Descriptors DEC
ALKYLATED AROMATICS; AROMATICS; CHROMATOGRAPHY; ELECTROMAGNETIC RADIATION; ELEMENTS; FLUIDS; HYDROCARBONS; IRRADIATION; LASER SPECTROSCOPY; LIQUID COLUMN CHROMATOGRAPHY; NONMETALS; ORGANIC COMPOUNDS; RADIATIONS; SEPARATION PROCESSES; SPECTRA; SPECTROSCOPY