Synergism in hexavalent uranium extraction with mixtures of 1-phenyl-3-methyl-4-benzoylpyrazolone-5 and some donor-active substances
Creators
Description
U(6) extraction in the systems 0.1 mol/l HNO3-1-phenyl-3-methyl-4-benzoylpyrazolone-5-tributyl phosphate (or trioctylphosphine oxide-benzene, or cyclohexane) is investigated. A considerable synergism is detected, the regions of its maximum manifestation are clarified. The composition of the compounds extracted is determined, the constants of uranium extraction in the systems PMBR-TBP being calculated. The comparison of the results on synergistic extraction of uranium with previously obtained results on Am (3) extraction in the same systems has shown that the maximum values of synergistic effect for the elements are manifested in different regions of the reagent concentrations. These two cases are the examples of a possibility of synergism use to improve the element separation
Additional details
Additional titles
- Original title (Russian)
- Синергетический эффект при экстракции шестивалентного урана смесями 1-фенил-3metil-4-бензоилпиразолона-5 и некоторых донорноактивных веществ
Publishing Information
- Journal Title
- Radiokhimiya
- Journal Volume
- 23
- Journal Issue
- 4
- Series
- Radiokhimiya.
- Journal Page Range
- 521-527
- ISSN
- 0033-8311
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 13661179
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHELATING AGENTS; CHEMICAL REACTION KINETICS; KETONES; NITRIC ACID; PYRAZOLES; SOLVENT EXTRACTION; SYNERGISM; TBP; URANYL COMPLEXES; URANYL NITRATES
- Descriptors DEC
- ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; AZOLES; BUTYL PHOSPHATES; COMPLEXES; ESTERS; HETEROCYCLIC COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; KINETICS; NITRATES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORIC ACID ESTERS; REACTION KINETICS; SEPARATION PROCESSES; URANIUM COMPLEXES; URANIUM COMPOUNDS; URANYL COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Soviet Radiochemistry (USA).