Published 1986 | Version v1
Report

Lower bounds to ground state eigenvalues of the Schroedinger equation via optimized inner projection: application to quartic and sextic anharmonic oscillators

  • 1. Univ. of Waterloo, Ontario

Description

Inner projection combined with bracketing techniques represents a very powerful method of calculating lower bounds to eigenvalues of the Schroedinger equation. The Hamiltonian is expressed as a sum of an unperturbed operator (whose eigenvalue equation is soluble) and a perturbed operator that should be positive definite. For small values of the coupling constant, the conventional splitting of the Hamiltonian is adequate. For strong coupling, however, it is advantageous to partition the Hamiltonian in an optimized fashion, accomplished by an appropriate scaling of the space coordinates and momenta. This optimized inner projection (OIP) method yields remarkably good results for all values of the coupling constant, even for manifolds of minimal dimensionality

Additional details

Publishing Information

Imprint Title
Proceedings of the International Symposium on atomic, molecular and solid-state theory, scattering problems, many body phenomena, and computational quantum chemistry: quantum chemistry symposium No. 20
Journal Page Range
p. 65-72.
Report number
DOE/ER/60420--1

Conference

Title
Special Sanibel symposium.
Dates
8 Mar 1986.
Place
St. Augustine, FL (USA).

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
19009553
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
ALGORITHMS; ANHARMONIC OSCILLATORS; BOUNDARY CONDITIONS; COUPLING; EIGENVALUES; HAMILTONIANS; MATHEMATICAL MODELS; MATHEMATICAL OPERATORS; NUMERICAL SOLUTION; PERTURBATION THEORY; QUANTUM MECHANICS; SCHROEDINGER EQUATION
Descriptors DEC
DIFFERENTIAL EQUATIONS; EQUATIONS; MECHANICS; PARTIAL DIFFERENTIAL EQUATIONS; QUANTUM OPERATORS; WAVE EQUATIONS