Lower bounds to ground state eigenvalues of the Schroedinger equation via optimized inner projection: application to quartic and sextic anharmonic oscillators
Description
Inner projection combined with bracketing techniques represents a very powerful method of calculating lower bounds to eigenvalues of the Schroedinger equation. The Hamiltonian is expressed as a sum of an unperturbed operator (whose eigenvalue equation is soluble) and a perturbed operator that should be positive definite. For small values of the coupling constant, the conventional splitting of the Hamiltonian is adequate. For strong coupling, however, it is advantageous to partition the Hamiltonian in an optimized fashion, accomplished by an appropriate scaling of the space coordinates and momenta. This optimized inner projection (OIP) method yields remarkably good results for all values of the coupling constant, even for manifolds of minimal dimensionality
Additional details
Publishing Information
- Imprint Title
- Proceedings of the International Symposium on atomic, molecular and solid-state theory, scattering problems, many body phenomena, and computational quantum chemistry: quantum chemistry symposium No. 20
- Journal Page Range
- p. 65-72.
- Report number
- DOE/ER/60420--1
Conference
- Title
- Special Sanibel symposium.
- Dates
- 8 Mar 1986.
- Place
- St. Augustine, FL (USA).
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19009553
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Resource subtype / Literary indicator
- Conference, Non-conventional Literature
- Descriptors DEI
- ALGORITHMS; ANHARMONIC OSCILLATORS; BOUNDARY CONDITIONS; COUPLING; EIGENVALUES; HAMILTONIANS; MATHEMATICAL MODELS; MATHEMATICAL OPERATORS; NUMERICAL SOLUTION; PERTURBATION THEORY; QUANTUM MECHANICS; SCHROEDINGER EQUATION
- Descriptors DEC
- DIFFERENTIAL EQUATIONS; EQUATIONS; MECHANICS; PARTIAL DIFFERENTIAL EQUATIONS; QUANTUM OPERATORS; WAVE EQUATIONS