Published August 1990
| Version v1
Journal article
Study of [NiMo9O32]6- anion and its interaction with d- and f-element ions in aqueous solutions using 17O, 95Mo and other nuclei NMR
- 1. AN SSSR, Novosibirsk (USSR). Inst. Kataliza
- 2. Moskovskij Gosudarstvennyj Univ., Moscow (USSR)
Description
By the 95Mo, 17O, 139La and 67Zn NMR interaction of [NiMo9O32]6- heteropolyanion with La3+, Pr3+, Zn2+ and Ni2+ is investigated. It is shown that only in the case of f-elements a complex, labile in the NMR time scale, is formed. In its formation as-MoO2-groupings of heteropolyligands take part. 17O NMR spectra of [NiMo9O32]6- enriched solution has been obtained and described for the first time. Application of 95Mo, 17O NMR permitted to prove the preservation of the anion structure in aqueous solution
Additional details
Additional titles
- Original title (Russian)
- Исследование аниона [NiMo
Publishing Information
- Journal Title
- Zhurnal Neorganicheskoj Khimii
- Journal Volume
- 35
- Journal Issue
- 8
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 2100-2103
- ISSN
- 0044-457X
- CODEN
- ZNOKA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 22041790
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANIONS; AQUEOUS SOLUTIONS; CHEMICAL PREPARATION; HETEROPOLYANIONS; LANTHANUM COMPLEXES; MOLECULAR STRUCTURE; MOLYBDENUM COMPOUNDS; NICKEL COMPOUNDS; NMR SPECTRA; OXYGEN COMPOUNDS; PRASEODYMIUM COMPLEXES; ZINC COMPOUNDS
- Descriptors DEC
- CHARGED PARTICLES; COMPLEXES; DISPERSIONS; HOMOGENEOUS MIXTURES; IONS; MIXTURES; RARE EARTH COMPLEXES; SOLUTIONS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS