Published October 15, 1979 | Version v1
Journal article

Quantum mechanical implications of classical ergodicity

  • 1. Department of Chemistry and Materials and Molecular Research Division of the Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720

Description

The concept of quantum ergodicity is examined empirically through a quantitative study of the eigenfunctions of both the Barbanis and Casati--Ford potentials. By considering the behavior of the nodes of the wave functions and by employing a combination of natural orbital and spectral analyses, many of the higher eigenstates can apparently be classified as ergodic. These particular states seem to correspond quite well not only to classical ergodic trajectories but also to (currently) unquantizable semiclassical wave functions. The relationship between this quantal ergodicity and its classical equivalent is discussed

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
71
Journal Issue
8
Series
J. Chem. Phys.
Journal Page Range
3311-3322
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
11514955
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
CHEMICAL REACTION KINETICS; ERGODIC HYPOTHESIS; PHASE SPACE; QUANTUM MECHANICS; STOCHASTIC PROCESSES; WAVE FUNCTIONS
Descriptors DEC
FUNCTIONS; HYPOTHESIS; KINETICS; MATHEMATICAL SPACE; MECHANICS; REACTION KINETICS; SPACE