Published October 15, 1979
| Version v1
Journal article
Quantum mechanical implications of classical ergodicity
Creators
- 1. Department of Chemistry and Materials and Molecular Research Division of the Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
Description
The concept of quantum ergodicity is examined empirically through a quantitative study of the eigenfunctions of both the Barbanis and Casati--Ford potentials. By considering the behavior of the nodes of the wave functions and by employing a combination of natural orbital and spectral analyses, many of the higher eigenstates can apparently be classified as ergodic. These particular states seem to correspond quite well not only to classical ergodic trajectories but also to (currently) unquantizable semiclassical wave functions. The relationship between this quantal ergodicity and its classical equivalent is discussed
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 71
- Journal Issue
- 8
- Series
- J. Chem. Phys.
- Journal Page Range
- 3311-3322
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 11514955
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; ERGODIC HYPOTHESIS; PHASE SPACE; QUANTUM MECHANICS; STOCHASTIC PROCESSES; WAVE FUNCTIONS
- Descriptors DEC
- FUNCTIONS; HYPOTHESIS; KINETICS; MATHEMATICAL SPACE; MECHANICS; REACTION KINETICS; SPACE