Published 2014
| Version v1
Book
Quantification and isotope ratio measurement of boron in U3Si2 by inductively coupled plasma mass spectrometry
- 1. Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
- 2. Integral Fuel Fabrication Facility, Bhabha Atomic Research Centre, Mumbai (India)
Description
An analytical methodology was developed for precise quantification and isotope ratio measurement of boron in U3Si2 matrix by using ICP-MS after matrix separation. The analytical technique was validated by recovery studies employing standard addition method and the accuracy in isotope ratio measurement was improved by correcting the bias factor after analyzing NIST SRM951. The quantification of B in the three U3Si2 samples was found in the range of 2.32-3.90 μg g-1 with a maximum standard deviation of 3%. The 10B/11B value in the three samples was found to be 0.2455±0.0042, 0.2451±0.0036 and 0.2452±0.0041. (author)
Additional details
Publishing Information
- Publisher
- Bhabha Atomic Research Centre
- Imprint Place
- Mumbai (India)
- Imprint Title
- Proceedings of the DAE-BRNS fifth symposium on nuclear analytical chemistry
- Imprint Pagination
- 603 p.
- Journal Page Range
- p. 284-285
Conference
- Title
- 5. DAE-BRNS symposium on nuclear analytical chemistry
- Acronym
- NAC-V
- Dates
- 20-24 Jan 2014
- Place
- Mumbai (India)
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 45055639
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- BORON 10; BORON 11; ICP MASS SPECTROSCOPY; ISOTOPE RATIO; URANIUM SILICIDES
- Descriptors DEC
- ACTINIDE COMPOUNDS; BORON ISOTOPES; DIMENSIONLESS NUMBERS; ISOTOPES; LIGHT NUCLEI; MASS SPECTROSCOPY; NUCLEI; ODD-EVEN NUCLEI; ODD-ODD NUCLEI; SILICIDES; SILICON COMPOUNDS; SPECTROSCOPY; STABLE ISOTOPES; URANIUM COMPOUNDS
Optional Information
- Notes
- 7 refs., 2 tabs.