Published March 1989 | Version v1
Journal article Metadata-only

Comparative study of radiation-induced thin-layer polymerization of acrylic and methacrylic esters

Creators

  • 1. Nauchno-Issledovatel'skij Fiziko-Khimicheskij Inst., Moscow (USSR)

Description

Comparative study of polymerization of certain acrylic esters (AE) and their methacrylic analogues in a thin (∼ 200 μm) layer under the effect of accelerated electrons (E 600 keV, J = 1 mA) has been carried out. A sharp decrease in polymerization rate was always observed when passing from AE to ME. It is shown that in the process of AE and ME polymerization anionic mechanism makes a considerable contribution to the overall process. The mechanism causes the differences in the process course and polymer properties from AE to ME

Additional details

Additional titles

Original title (Russian)
Сравнительное рассмотрение радиационной полимеризации в тонком слое акриловых и метакриловых эфиров

Publishing Information

Journal Title
Khimiya Vysokikh Ehnergij
Journal Volume
23
Journal Issue
2
Series
Khim. Vys. Ehnerg.
Journal Page Range
177-178
ISSN
0023-1193
CODEN
KHVKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
20075093
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ACRYLIC ACID ESTERS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; COMPARATIVE EVALUATIONS; ELECTRON BEAMS; KEV RANGE 100-1000; LAYERS; METHACRYLIC ACID ESTERS; POLYMERIZATION
Descriptors DEC
BEAMS; CARBOXYLIC ACID ESTERS; CHEMICAL REACTIONS; ENERGY RANGE; ESTERS; EVALUATION; KEV RANGE; KINETICS; LEPTON BEAMS; ORGANIC COMPOUNDS; PARTICLE BEAMS; RADIATION EFFECTS; REACTION KINETICS