Published February 2006
| Version v1
Journal article
57Fe Moessbauer spectra and magnetic data from the kagome antiferromagnet H3O-jarosite
- 1. C.E.A.- Saclay, Service de Physique de l'Etat Condense, URA 2464 (CNRS) (France)
- 2. Universite Montpellier II, Laboratoire des Agregats Moleculaires et Materiaux Inorganiques, UMR 5072 (CNRS) (France)
- 3. University College London, Department of Chemistry (United Kingdom)
Description
57Fe Moessbauer spectra are presented from (H3O)Fe3(SO4)2(OH)6 (or H3O-jarosite), which is a model kagome antiferromagnet which features geometrical frustration and spin-glass-like behaviour. Dynamic scaling of the freezing temperature as a function of frequency is observed over a large frequency range, which indicates the presence of a spin-glass transition. A fast relaxation model between 'up' and 'down' states, separated by an energy gap, is presented to account for the shape of the Moessbauer spectra below the freezing temperature. From a calculation of the Electric Field Gradient tensor, it is suggested that H3O-jarosite is an XY-Heisenberg antiferromagnet, where the Fe3+ moments lie in the kagome planes.
Additional details
Identifiers
Publishing Information
- Journal Title
- Hyperfine Interactions
- Journal Volume
- 168
- Journal Issue
- 1-3
- Journal Page Range
- p. 1085-1089
- ISSN
- 0304-3843
- CODEN
- HYINDN
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 43029926
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- ANTIFERROMAGNETIC MATERIALS; ELECTRIC FIELDS; ENERGY GAP; FREEZING; FREQUENCY DEPENDENCE; FREQUENCY RANGE; HYDROGEN COMPOUNDS; IRON 57; IRON COMPOUNDS; IRON IONS; MOESSBAUER EFFECT; OXYGEN COMPOUNDS; RELAXATION; SCALING; SPIN GLASS STATE; SULFATES; SULFUR COMPOUNDS
- Descriptors DEC
- CHARGED PARTICLES; EVEN-ODD NUCLEI; INTERMEDIATE MASS NUCLEI; IONS; IRON ISOTOPES; ISOTOPES; MAGNETIC MATERIALS; MATERIALS; NUCLEI; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; STABLE ISOTOPES; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2007 Springer Science+Business Media, Inc.