Published February 2006 | Version v1
Journal article

57Fe Moessbauer spectra and magnetic data from the kagome antiferromagnet H3O-jarosite

  • 1. C.E.A.- Saclay, Service de Physique de l'Etat Condense, URA 2464 (CNRS) (France)
  • 2. Universite Montpellier II, Laboratoire des Agregats Moleculaires et Materiaux Inorganiques, UMR 5072 (CNRS) (France)
  • 3. University College London, Department of Chemistry (United Kingdom)

Description

57Fe Moessbauer spectra are presented from (H3O)Fe3(SO4)2(OH)6 (or H3O-jarosite), which is a model kagome antiferromagnet which features geometrical frustration and spin-glass-like behaviour. Dynamic scaling of the freezing temperature as a function of frequency is observed over a large frequency range, which indicates the presence of a spin-glass transition. A fast relaxation model between 'up' and 'down' states, separated by an energy gap, is presented to account for the shape of the Moessbauer spectra below the freezing temperature. From a calculation of the Electric Field Gradient tensor, it is suggested that H3O-jarosite is an XY-Heisenberg antiferromagnet, where the Fe3+ moments lie in the kagome planes.

Additional details

Identifiers

Publishing Information

Journal Title
Hyperfine Interactions
Journal Volume
168
Journal Issue
1-3
Journal Page Range
p. 1085-1089
ISSN
0304-3843
CODEN
HYINDN

Optional Information

Copyright
Copyright (c) 2007 Springer Science+Business Media, Inc.