Published September 1994
| Version v1
Journal article
Sorption of hexane and cyclohexane liquids in high silica zeolite and boron-zeotype materials
Creators
- 1. Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Nuclear Materials Div
- 2. National Atomic Energy, Jakarta (Indonesia)
- 3. Salford Univ., (United Kingdom). Dept of Chemistry and Applied Chemistry
Description
Pentasil high silica zeolites (ZSM-5, ZSM-11) and their structural analog boron zeotypes (ZSM5-B, ZSM11-B) and Al-free silicates have been examined for the sorption of liquid n-hexane and cyclohexane by thermogravimetric constant coverage method. Effect of adsorbates on the framework topology and unit cell dimensions were also studied. The cell volume of boron-substituted samples were found to be significantly smaller than Al-substituted. Crystallinity of the samples were estimated from the framework of IR spectroscopy, differential thermal analysis, X-ray diffraction and adsorption of n-hexane techniques. (author)
Additional details
Publishing Information
- Journal Title
- Journal of the Chemical Society of Pakistan
- Journal Volume
- 16
- Journal Issue
- 3
- Journal Page Range
- p. 174-183.
- ISSN
- 0253-5106
- CODEN
- JCSPDF
INIS
- Country of Publication
- Pakistan
- Country of Input or Organization
- Pakistan
- INIS RN
- 27012872
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ADSORPTION; ALKANES; BORON; INFRARED SPECTRA; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION; ZEOLITES
- Descriptors DEC
- CHEMICAL ANALYSIS; COHERENT SCATTERING; DIFFRACTION; ELEMENTS; GRAVIMETRIC ANALYSIS; HYDROCARBONS; INORGANIC ION EXCHANGERS; ION EXCHANGE MATERIALS; MATERIALS; MINERALS; ORGANIC COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SEMIMETALS; SILICATE MINERALS; SORPTION; SPECTRA; THERMAL ANALYSIS