Published September 7, 1988
| Version v1
Journal article
Synthesis and characterization of Mo(nor)4 (nor = 1-norbornyl)
Creators
- 1. Massachusetts Institute of Technology, Cambridge (USA)
Description
A preparation of Mo(nor)4 (nor = 1-norbornyl) is described in detail. The complex was found to be stable to oxygen but to decompose in the presence of moisture. Mo(nor)4 did not react with pyridine, propylene oxide, 3-hexyne, 1 equivalent of CO, or 2,6-dimethylphenol in refluxing toluene. It was concluded that the large size of the molybdenum (IV) versus chromium (IV) is not enough to allow Mo(nor)4 to react readily with small molecules, certainly not dinitrogen. 22 references, 2 figures
Additional details
Publishing Information
- Journal Title
- Inorganic Chemistry
- Journal Volume
- 27
- Journal Issue
- 18
- Series
- Inorg. Chem.
- Journal Page Range
- 3253-3255
- ISSN
- 0020-1669
- CODEN
- INOCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 21001563
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CYCLOALKENES; DEUTERIUM; ISOTOPE EFFECTS; MOLYBDENUM COMPLEXES; NITROGEN; NUCLEAR MAGNETIC RESONANCE; PROTONS; TRACER TECHNIQUES
- Descriptors DEC
- ALKENES; BARYONS; CATIONS; CHARGED PARTICLES; COMPLEXES; ELEMENTARY PARTICLES; ELEMENTS; FERMIONS; HADRONS; HYDROCARBONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; HYDROGEN ISOTOPES; IONS; ISOTOPE APPLICATIONS; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; NONMETALS; NUCLEI; NUCLEONS; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; RESONANCE; STABLE ISOTOPES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES