Published 2000
| Version v1
Journal article
Structural properties of a dimeric phenylcyanamidocopper(l) complex, [{Cu(PPh3)2(C6H5NCN)}2]
- 1. Massey University, Palmerston North, (New Zealand). Chemistry-Institute of Fundamenal Sciences
- 2. Griffith University, Brisbane, (Australia). School of Science
Description
The X-ray crystal structure determination of bis[μ-(phenylcyanamido)bis(triphenylphosphine)copper(l)], [Cu(PPh3)2(C6H5NCN)2], (1) is reported. The complex has a centrosymmetric dimeric structure with the phenylcyanamide ligands bridging the copper atoms in a μ-1 ,3-fashion. The structure is compared with that of the 4-methylphenylcyanamido complex, [{Cu(PPh3)2(4-MeC6H4NCN)}2] (2), and the differences observed in the Cu-P bond lengths compared with changes in the solid state 31p cross-polarization magic-angle spinning (CPMAS) spectra of the two complexes. Copyright (2000) CSIRO Australia
Additional details
Identifiers
Publishing Information
- Journal Title
- Australian Journal of Chemistry
- Journal Volume
- 53
- Journal Issue
- 11-12
- Journal Page Range
- p. 971-973
- ISSN
- 0004-9425
- CODEN
- AJCHAS
INIS
- Country of Publication
- Australia
- Country of Input or Organization
- Australia
- INIS RN
- 33001100
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CHEMICAL PREPARATION; COPPER COMPLEXES; CRYSTALLOGRAPHY; DATA ANALYSIS; EXPERIMENTAL DATA; LIGANDS; MOLECULAR ORBITAL METHOD; NMR SPECTRA; PHOSPHINES; PHOSPHORUS 31; STRUCTURAL CHEMICAL ANALYSIS
- Descriptors DEC
- CALCULATION METHODS; COMPLEXES; DATA; INFORMATION; ISOTOPES; LIGHT NUCLEI; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; PHOSPHORUS COMPOUNDS; PHOSPHORUS ISOTOPES; SPECTRA; STABLE ISOTOPES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- 7 refs., 3 tabs., 1 fig. Full text (PDF) articles available from the publisher's Web site (subscription required) at http://www.publish.csiro.au/journals/ajc/