Observations of atmospheric lead-210 over the Atlantic Ocean and Antarctica during the FINNARP-1999/2999 Expedition

Physical and chemical properties of the atmosphere were measured in November-December 1999 onboard the Russian research vessel Akademik Fedorov over the Atlantic Ocean between the English Channel and the coast of Antarctica. After the cruise the measurements were continued in January 2000 at the Finnish research station Aboa (73 deg. 03'S, 13 deg. 25'W, 470 m above sea level) in Dronning Maud Land, Antarctica. The location of the station is about 170 km inland from the coast of Weddell Sea. The study is part of the Finnish Antarctic Research Programme (FINNARP) financed by the Academy of Finland. The observed 210Pb activity concentrations in the air varied between 24 and 790 μBq/m3 during the cruise between the English Channel and Cape town. The highest values were recorded close (<300-400 km) to the West-African coast between Senegal and Liberia. This coincides with the observations of highest aerosol optical thickness and light scattering coefficients. The latter observation can be attributed to two factors, biomass burning in Western Africa or resuspension of soil in the Sahara desert. Because anthropogenic activities have a negligible effect to the amount of lead-210 in the air, the resuspension in the Sahara desert is a more plausible explanation. Between Cape Town and the coast of Antarctica the observed 210Pb activity concentrations varied between <10 and 51 μBq/m3. At the research station Aboa the observed values varied between <10 and 37 μBq/m3. Between 6 and 11 January 2000 the air masses at Aboa originated from central regions of Antarctica according to the trajectory calculations made with the NORA Hysplit model. The concentrations were below detection limit between 11 and 14 January. These samples were connected to the air masses originating from the South Atlantic Ocean. Between 14 and 20 January air masses came to Aboa mainly from easterly direction from coastal and inland regions of the Antarctica. (LN)