Published 1977
| Version v1
Journal article
The crystal and molecular structure of trans-dioxobic (ethylenediamine) rhenium (5) perrhenate ReO2en2ReO4
- 1. Wroclaw Univ. (Poland) Inst. Chemii
Description
The yellow complex ReO3en was obtained and it was found to have the ReO2en2ReO4 formula. The ReO2en2ReO4 complex salt crystallizes in the centrosymmetric orthorhombic space group Dsub(2h)16-Pnma with a = 11,49(3), b = 17.85(5), c = 5.64(2)A, Z = 4. The data to sin THETA/lambda=0.65 (cuKsub(α) radiation) were collected by the Weissenberg method. The structure was solved by a combination of Patterson, Fourier and least-squares refinement techniques to an R value of 0.101 for 509 independent nonzero reflections. The rhenium atom occupies the symmetry centre and therefore the O-Re-O grouping in ReO2enB2+ cation is linear. (author)
Additional details
Publishing Information
- Journal Title
- Bull. Acad. Pol. Sci., Ser. Sci. Chim.
- Journal Volume
- 25
- Journal Issue
- 4
- Series
- Bull. Acad. Pol. Sci., Ser. Sci. Chim.
- Journal Page Range
- 271-276
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 10490346
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CRYSTAL STRUCTURE; EDTA; EXPERIMENTAL DATA; INFRARED SPECTRA; ISOLATED VALUES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; ORTHORHOMBIC LATTICES; PERRHENATES; RHENIUM COMPLEXES; SPACE GROUPS
- Descriptors DEC
- AMINO ACIDS; CARBOXYLIC ACIDS; CHELATING AGENTS; COMPLEXES; CRYSTAL LATTICES; DATA; DATA FORMS; INFORMATION; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; RHENIUM COMPOUNDS; SPECTRA; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS