Published 2013 | Version v1
Miscellaneous Metadata-only

Deuterium isotope effects, ΔpK = pKD2O - pKH2O, on the second dissociation of carbonic acid by Raman spectroscopy

Creators

  • 1. Univ. of Guelph, Dept. of Chemistry, Guelph, Ontario, (Canada)

Description

Polarized Raman spectroscopy has been used to measure the deuterium isotope effect, ΔpK = pKD2O - pKH2O, for the second ionization constant of carbonic acid in the temperature range of 25 oC to 125 oC, CO32- + D2O ⇋ DCO3- + OD-. Results for the light water pK dependence on temperature were compared to literature, confirming the reliability of the method. (author)

Part of:
Nuclear the next generation. 34th Annual Canadian Nuclear Society conference and 37th CNS/CNA student conference

Additional details

Publishing Information

Publisher
Canadian Nuclear Society
Imprint Place
Toronto, Ontario (Canada)
ISBN
978-1-926773-13-1
Imprint Title
Nuclear the next generation. 34th Annual Canadian Nuclear Society conference and 37th CNS/CNA student conference
Imprint Pagination
78 Megabytes
Journal Page Range
[5 p.]

Conference

Title
34. Annual Canadian Nuclear Society conference; 37. CNS/CNA student conference
Dates
9-12 Jun 2013
Place
Toronto, Ontario (Canada)

INIS

Country of Publication
Canada
Country of Input or Organization
Canada
INIS RN
47120227
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
CARBONIC ACID; DEUTERIUM; HYDROGEN ISOTOPES; IONIZATION; WATER
Descriptors DEC
CARBON COMPOUNDS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INORGANIC ACIDS; INORGANIC COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; OXYGEN COMPOUNDS; STABLE ISOTOPES

Optional Information

Notes
7 refs., 3 figs.