Published 1999 | Version v1
Journal article Metadata-only

Synthesis and study of lutetium complexes with octaphenyltetraazaporphin

Creators

  • 1. Ivanovskaya Gosudarstvennaya Khimiko-Tekhnologicheskaya Akademiya, Ivanovo (Russian Federation)

Description

Proceeding from diphenylmaleinodinitride and lutetium chloride, chlorolutetiumoctaphenyltetraazaporphin is synthesized, its further heating with excess of phthalodinitrile giving rise to formation of a sandwich-type structure complex, combining octaphenyltetraazaporphin and phthalocyanine ligands at lutetium atom. Spectral properties of the synthesized compounds are studied. Specific features of their electron absorption spectra compared with spectra of the known lutetium complexes with phthalocyanine are pointed out

Abstract (Russian)

Исходя из дифенилмалеинодинитрила и хлорида лютеция, синтезтрован хлоролютецийоктафенилтетраазапорфин, из которого в дальнейшем при нагревании с избытком фталодинитрила получен комплекс сандвичевой структуры, сочетающий при атоме лютеция октафенилтетразапорфиновый и фталоцианиновый лиганды. Исследованы спектральные свойства синтезированных соединений. Отмечены особенности их электронных спектров поглощения по сравнению со спектрами известных комплексов лютеция с фталоцианином

Additional details

Additional titles

Original title (Russian)
Синтез и исследование комплексов лютеция с октафенилтетраазапорфином

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
69
Journal Issue
1
Journal Page Range
p. 146-149
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32008858
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; AZAARENES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHLORIDES; LUTETIUM COMPLEXES; MOLECULAR STRUCTURE; PHTHALOCYANINES; PORPHYRINS
Descriptors DEC
AROMATICS; CARBOXYLIC ACIDS; CHLORINE COMPOUNDS; COMPLEXES; DYES; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RARE EARTH COMPLEXES; SPECTRA; SYNTHESIS; YIELDS

Optional Information

Notes
8 refs., 4 figs.