Published November 2009 | Version v1
Journal article

Field theory for classical systems. Entropic effects. Application to non homogeneous electrolytes

  • 1. Laboratory of Electrochemistry, Chemistry of Interfaces and Modeling for Energy, Chimie Paris University, Raris (France)
  • 2. Institute for Condensed Matter Physics, Lviv (Ukraine)

Description

In contrast to other field theory approaches, we do not start from Gibbs partition function in terms of particles. The direct use of a field theory assumption leads to a simple formulation in terms of a Hamiltonian functional. The form of this functional party reminiscent of other field theory approaches and of the density functional theory. However, the formal similarity of the functional is misleading. In this paper, we intend to clarify some aspects which may lead to confusion when interpreting this field theory approach. We compare the role of quantum effects in the traditional approach and in field theory.

Additional details

Publishing Information

Journal Title
Zhurnal Fyizichnikh Doslyidzhen'
Journal Volume
13
Journal Issue
no.4
Journal Page Range
p. 4002
ISSN
1027-4642

Conference

Title
3. Conference on Statistical Physics
Dates
23-25 Jun 2009
Place
Lviv (Ukraine)