Published November 2009
| Version v1
Journal article
Field theory for classical systems. Entropic effects. Application to non homogeneous electrolytes
Creators
- 1. Laboratory of Electrochemistry, Chemistry of Interfaces and Modeling for Energy, Chimie Paris University, Raris (France)
- 2. Institute for Condensed Matter Physics, Lviv (Ukraine)
Description
In contrast to other field theory approaches, we do not start from Gibbs partition function in terms of particles. The direct use of a field theory assumption leads to a simple formulation in terms of a Hamiltonian functional. The form of this functional party reminiscent of other field theory approaches and of the density functional theory. However, the formal similarity of the functional is misleading. In this paper, we intend to clarify some aspects which may lead to confusion when interpreting this field theory approach. We compare the role of quantum effects in the traditional approach and in field theory.
Additional details
Publishing Information
- Journal Title
- Zhurnal Fyizichnikh Doslyidzhen'
- Journal Volume
- 13
- Journal Issue
- no.4
- Journal Page Range
- p. 4002
- ISSN
- 1027-4642
Conference
- Title
- 3. Conference on Statistical Physics
- Dates
- 23-25 Jun 2009
- Place
- Lviv (Ukraine)
INIS
- Country of Publication
- Ukraine
- Country of Input or Organization
- Ukraine
- INIS RN
- 42083101
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CLASSICAL MECHANICS; COULOMB FIELD; ELECTROLYTES; ENTROPY; FUNCTIONAL MODELS; HAMILTONIANS; PARTITION FUNCTIONS; QUANTUM FIELD THEORY; QUANTUM MECHANICS; THERMODYNAMICS
- Descriptors DEC
- ELECTRIC FIELDS; FIELD THEORIES; FUNCTIONS; MATHEMATICAL OPERATORS; MECHANICS; PHYSICAL PROPERTIES; QUANTUM OPERATORS; THERMODYNAMIC PROPERTIES