Published 1987 | Version v1
Journal article Metadata-only

Crystal structure of chloryl tetrafluoroborate, ClO2+BF4- at -120 deg C

Creators

Description

Synthesis of chloryl tetrafluovoborate, formed under BF3 reaction with CF3 in the presence of moisture traces, is performed and its x-ray diffraction investigation is made. Monoclinic crystal lattice parameters at -120 deg C are: a=5.427(3), b=8.517(5), c=9.446 (5)A, β=97.97(4) deg, v=432.4(3)A03, Z=4, sp. gr. Cc. ClO2+BF4- structure is formed of alternating layers of BF4--anions and ClO2+ - cations of angular structure. B-F bond lengths in distorted tetrahedric BF4--anion are changed from 1.385(1) to 1.411(1)A

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура тетрафторбората хлорила ClO

Publishing Information

Journal Title
Dokl. Akad. Nauk SSSR
Journal Volume
293
Journal Issue
5
Series
Dokl. Akad. Nauk SSSR.
Journal Page Range
1152-1155
ISSN
0002-3264
CODEN
DANKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
19016501
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; BORON COMPLEXES; CHEMICAL BONDS; CHEMICAL PREPARATION; CHLORINE COMPOUNDS; FLUORIDES; LATTICE PARAMETERS; LOW TEMPERATURE; MONOCLINIC LATTICES; MONOCRYSTALS; OXYGEN COMPOUNDS; SPACE GROUPS
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS