Semiclassical quantization via adiabatic switching. I. Choice of tori and initial conditions for two-dimensional systems
Creators
- 1. Department of Chemistry, University of Southern California, Los Angeles, California 90089-0482
Description
A general theoretical base and a general strategy for implementing semiclassical quantization using the adiabatic-switching method are presented for two-dimensional systems. The method proposed does not depend on specialized coordinates, trajectory, or surfaces-of-section studies and is generalizable to multidimensional systems. The choice of the initial tori for the switching procedure is accomplished by simple diagonalizations of small-dimensional matrix representations of invariant operators obtained from perturbation theory. The method gives quantum energies at a useful level of accuracy for the vast majority of states in many of the well-known nonresonant and resonant Hamiltonian cases. Many eigenvalues previously thought unobtainable when the adiabatic-switching method is used are obtained in a quite simple manner
Additional details
Publishing Information
- Journal Title
- Physical Review, A
- Journal Volume
- 38
- Journal Issue
- 8
- Series
- Phys. Rev., A.
- Journal Page Range
- 3877-3899
- ISSN
- 0556-2791
- CODEN
- PLRAA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 20000403
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOMIC IONS; CORRELATIONS; CROSS SECTIONS; ELECTRON-MOLECULE COLLISIONS; EXCITATION; IONIZATION; MOLECULAR IONS; OXYGEN; SHOCK HEATING; VIBRATIONAL STATES
- Descriptors DEC
- CHARGED PARTICLES; COLLISIONS; ELECTRON COLLISIONS; ELEMENTS; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; EXCITED STATES; HEATING; IONS; MOLECULE COLLISIONS; NONMETALS; PLASMA HEATING