Published April 1976
| Version v1
Journal article
Rhodium thioacetate complexes
- 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
Description
Thioacetato-complexes of rhodium(II) were prepared by the reaction of thioacetic acid with rhodium(II) carboxylates. Diamagnetic compounds of the type Rh2(CH3COS)42A, where A=H2O, Py, N2H4.HCl, Thio, KNCS, DMSO, CH3CN, CsCl, or CH3COSH, were isolated. Their infrared spectra were recorded, and the principal vibrational wavenumbers assigned. The X-ray electron spectra confirm that rhodium is divalent. The thioacetato-complexes are dimeric, with a metal-metal bond. [Rh(NH3)5(CH3COS)]I2 was prepared, and its properties studied. The significant decrease in the strength of the bonds formed by the axial ligands with rhodium is due to the strong trans-influence of the covalent rhodium-rhodium sigma-bond
Additional details
Additional titles
- Original title (Russian)
- Тиоацетатные комплексы родия
Publishing Information
- Journal Title
- Zh. Neorg. Khim.
- Journal Volume
- 21
- Journal Issue
- 4
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 1085-1094
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 8314882
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETATES; CESIUM CHLORIDES; CHEMICAL PREPARATION; ELECTRON SPECTRA; INFRARED SPECTRA; ORGANIC SULFUR COMPOUNDS; RHODIUM COMPLEXES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBOXYLIC ACID SALTS; CESIUM COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- 21 refs.; for English translation see the journal Russ. J. Inorg. Chem.