Insights of Pb isotopic signature into the historical evolution and sources of Pb contamination in a sediment core of the southwestern Iberian Atlantic shelf

Stable Pb isotopic ratios and concentrations of Al, Cu and Pb were measured in a 5 m long sediment core (VC2B) retrieved at 96 m water depth in the southwestern Iberian Atlantic shelf. Five phases during the last 9.5 kyrs were identified, two of them (Roman Period and modern mining) marked by a decrease of ²⁰⁶Pb/²⁰⁷Pb ratios reflecting additional inputs of Pb derived from mining activities. The Roman Period was also characterized by high ²⁰⁸Pb/²⁰⁶Pb ratios suggesting the exploitation of the outcropping portion of the orebody intensely weathered when compared with the other formations later mined. The shift of ²⁰⁸Pb/²⁰⁶Pb ratios towards linearity took approximately 1.0 kyrs, which may mirror the time of environmental recovery from the impact of Roman mining activities. The application of a mixing model allowed the quantification of the contribution associated with anthropogenic mining activities to the shelf sediments. The maximum values of Pb contamination occurred in the 20^th century. This study gives direct evidence of Pb and Cu exploitation over the last 2000 years. The stable Pb isotopic signatures point to legacy of mining activities that are still the prevailing metal source recorded in the southwestern Iberian Atlantic shelf sediments. - Highlights: • Ancient (and modern) mining pressures are identified in the Iberian shelf sediments. • Two periods of Pb contamination associated with Roman and modern mining activities • The rise of Pb/Al ratios in sediments younger than 1850 CE is not related to textural variability. • Despite the end of mining the input of Pb (and Cu) into the environment continues. • Around 60% of anthropogenic Pb was attributed to mining activity in the 20^th century.