Published February 1998
| Version v1
Journal article
Synthesis and characterization of [(Ru(η6-C6Me6)Cl2)2 (μ-DCBT)] and its reaction with EPh3 (E= P, As, Sb), 2,2'-bipyridine and 1,10'-phenanthroline
- 1. Department of Chemistry, APS University, Rewa (India)
Description
Reaction of [(Ru(η6-C6Me6)Cl2)2] with 1,4-dicyano trans-2-butene gives a binuclear complex [(Ru(η6-C6Me6)Cl2)2 (μ-DCBT)] which undergoes metathetical reactions with EPh3 (E = P, As, Sb) and NN donor bases, viz. 2,2'-bipyridine and 1,10'-phenanthroline. The resulting products have been characterised by elemental analyses, IR, UV-Vis 1H and 13C NMR spectroscopy. (author)
Additional details
Publishing Information
- Journal Title
- Indian Journal of Chemistry. Section A: Inorganic, Bio-inorganic, Physical, Theoretical and Analytical Chemistry
- Journal Volume
- 37
- Journal Issue
- 2
- Journal Page Range
- p. 165-168
- CODEN
- ICACEC
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 30001305
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; CHEMICAL COMPOSITION; INFRARED SPECTRA; LIGANDS; NMR SPECTRA; PHENANTHROLINES; PYRIDINES; RUTHENIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; ULTRAVIOLET SPECTRA
- Descriptors DEC
- AROMATICS; AZAARENES; AZINES; COMPLEXES; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPECTRA; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- 25 refs., 1 tab.