Published September 2018 | Version v1
Journal article Metadata-only

Synthesis and physicochemical characterization of a new mixed-valence IronIII-ZincII diphosphate: Zn2+Fe3+2(P2O7)2

Creators

  • 1. Laboratory of Criospectroscopy and Biospectroscopy, Department of Chemistry, University of Coimbra, P-3004-535 Coimbra (Portugal)
  • 2. Chemistry Laboratory of Condensed Matter (LCMC), Faculty of Science and Technology Fez, University Sidi Mohammed Ben Abdellah, BP. 2202 (Morocco)
  • 3. CFisUC, Department of Physics, University of Coimbra, P-3004-512 (Portugal)

Description

Highlights: • New mixed-cation iron (III)-zinc(II) diphosphate. • Isostructure with Fe2+Fe3+2(P2O7)2. • New phosphate has Néel temperature about 5.5 K. • Mössbauer data confirms the presence of the Fe3+ in octahedral sites. • Paramagnetic behavior at room temperature of new diphosphate.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.matchemphys.2018.05.060

Additional details

Identifiers

DOI
10.1016/j.matchemphys.2018.05.060;
PII
S0254058418304656;

Publishing Information

Journal Title
Materials Chemistry and Physics
Journal Volume
216
Journal Page Range
p. 22-27
ISSN
0254-0584
CODEN
MCHPDR

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49097058
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
IRON IONS; PHOSPHATES; SYNTHESIS; TEMPERATURE RANGE 0273-0400 K; X-RAY DIFFRACTION
Descriptors DEC
CHARGED PARTICLES; COHERENT SCATTERING; DIFFRACTION; IONS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; SCATTERING; TEMPERATURE RANGE

Optional Information

Copyright
Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.