Phase transition analogous to Bose-Einstein condensation in systems of noninteracting surfactant aggregates
Creators
- 1. Department of Physics, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)
- 2. Grupo Interdisciplinar de Sistemas Complicados (GISC), Departamento de Matematicas, Universidad Carlos III de Madrid, Avenida de la Universidad 30, 28911 Leganes, Madrid (Spain)
Description
Ideal bosons and a classical system of monomers that aggregate forming noninteracting ring polymers are known to have the same partition function. So, the ring polymers have a phase transition, the analogue of Bose-Einstein condensation of bosons. At this phase transition macroscopic polymers are formed. The link between these systems is made via Feynman's path integrals: these integrals are the same for the trajectories of the bosons in imaginary time and for the configurations of the polymers. We show that a transition of this general form occurs within a whole class of aggregating systems. Examples are the lamellae formation in suspensions of disclike micelles or the emulsification failure observed in water-oil-surfactant emulsions. As with bosons, the transition occurs even when aggregates do not interact. The λ-transition in 4He is believed to be Bose-Einstein condensation modified by interatomic interactions. We suggest that interaggregate interactions too only modify the transition we have found
Additional details
Identifiers
Publishing Information
- Journal Title
- Physical Review. E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
- Journal Volume
- 65
- Journal Issue
- 3
- Journal Page Range
- p. 031406-031406.13
- ISSN
- 1063-651X
- CODEN
- PLEEE8
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36001662
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- BOSE-EINSTEIN CONDENSATION; BOSONS; EMULSIFICATION; EMULSIONS; FAILURES; FEYNMAN PATH INTEGRAL; HELIUM 4; LAMELLAE; LIQUIDS; MONOMERS; OILS; PARTITION FUNCTIONS; PHASE TRANSFORMATIONS; POLYMERS; SURFACTANTS; SUSPENSIONS; TRAJECTORIES; WATER
- Descriptors DEC
- COLLOIDS; DISPERSIONS; EVEN-EVEN NUCLEI; FLUIDS; FUNCTIONS; HELIUM ISOTOPES; HYDROGEN COMPOUNDS; INTEGRALS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; OTHER ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PATH INTEGRALS; STABLE ISOTOPES
Optional Information
- Notes
- (c) 2002 The American Physical Society