Published March 2002 | Version v1
Journal article

Phase transition analogous to Bose-Einstein condensation in systems of noninteracting surfactant aggregates

  • 1. Department of Physics, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)
  • 2. Grupo Interdisciplinar de Sistemas Complicados (GISC), Departamento de Matematicas, Universidad Carlos III de Madrid, Avenida de la Universidad 30, 28911 Leganes, Madrid (Spain)

Description

Ideal bosons and a classical system of monomers that aggregate forming noninteracting ring polymers are known to have the same partition function. So, the ring polymers have a phase transition, the analogue of Bose-Einstein condensation of bosons. At this phase transition macroscopic polymers are formed. The link between these systems is made via Feynman's path integrals: these integrals are the same for the trajectories of the bosons in imaginary time and for the configurations of the polymers. We show that a transition of this general form occurs within a whole class of aggregating systems. Examples are the lamellae formation in suspensions of disclike micelles or the emulsification failure observed in water-oil-surfactant emulsions. As with bosons, the transition occurs even when aggregates do not interact. The λ-transition in 4He is believed to be Bose-Einstein condensation modified by interatomic interactions. We suggest that interaggregate interactions too only modify the transition we have found

Additional details

Identifiers

Publishing Information

Journal Title
Physical Review. E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Journal Volume
65
Journal Issue
3
Journal Page Range
p. 031406-031406.13
ISSN
1063-651X
CODEN
PLEEE8

Optional Information

Notes
(c) 2002 The American Physical Society