Published June 2016 | Version v1
Journal article Metadata-only

Cluster helix structure of the binary compound W5I12

Creators

  • 1. Abteilung fuer Festkoerperchemie und Theoretische Anorganische Chemie, Institut fuer Anorganische Chemie, Universitaet Tuebingen (Germany)

Description

The binary tungsten iodide W5I12 forms an unprecedented one-dimensional helical structure. A crystal structure refinement performed on basis of X-ray powder diffraction data revealed the space group P61 [Z = 6, a = 993.97(2) pm, c = 4226.73(9) pm]. The crystal structure is based on [(W5I8i)I3aI2/2a-a] clusters, interconnected by two shared apical iodido ligands to form helical chain arrangements. (Copyright copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/zaac.201600131

Additional details

Identifiers

DOI
10.1002/zaac.201600131;

Publishing Information

Journal Title
Zeitschrift fuer anorganische und allgemeine Chemie (online)
Journal Volume
642
Journal Issue
11-12
Journal Page Range
p. 677-680
ISSN
1521-3749
CODEN
ZAACAB

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48070472
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTAL STRUCTURE; HELICAL CONFIGURATION; POWDERS; TUNGSTEN IODIDES; X-RAY DIFFRACTION
Descriptors DEC
COHERENT SCATTERING; CONFIGURATION; DIFFRACTION; HALIDES; HALOGEN COMPOUNDS; IODIDES; IODINE COMPOUNDS; REFRACTORY METAL COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS; TUNGSTEN HALIDES

Optional Information

Notes
With 4 figs., 2 tabs., 19 refs.