Visible-LED-light-driven photocatalytic degradation of ofloxacin and ciprofloxacin by magnetic biochar modified flower-like Bi2WO6: The synergistic effects, mechanism insights and degradation pathways

Highlights: • Bi₂WO₆/Fe₃O₄/BC exhibited excellent removal rates of ofloxacin and ciprofloxacin. • Fe₃O₄ and biochar promoted the light absorption property and charge separation. • O₂⁻ was the main active species in ofloxacin and ciprofloxacin degradation. • Hydroxylation and ring cleavage of these two drugs were main degradation pathway. • Bi₂WO₆/Fe₃O₄/BC had broad prospects in antibiotic-contaminated sewage treatment. Bi₂WO₆ possesses good stability but poor photocatalytic activity under visible light. Herein, the coupling of Bi₂WO₆, Fe₃O₄ and biochar (Bi₂WO₆/Fe₃O₄/BC) was investigated to enhance the photocatalytic performance of Bi₂WO₆ through facile hydrothermal method, which almost completely degraded ofloxacin (OFL) and ciprofloxacin (CIP) within 30 min under energy-saving visible LED irradiation. The superior photocatalytic activity of Bi₂WO₆/Fe₃O₄/BC was ascribed to the stronger visible light adsorption capacity and the lower recombination of electron-hole pairs. O₂⁻ played a major role during the photocatalytic reaction. The characterization results suggested that the introduction of biochar avoided the agglomeration of Bi₂WO₆ microspheres and Fe₃O₄ nanoparticles, at the same time, the biochar participated in OFL and CIP photodegradation by consuming different oxygen-containing functional groups. In order to further evaluate the application potential of Bi₂WO₆/Fe₃O₄/BC, the effects of environment factors and the application in different actual water were carefully investigated. Various transformation products and the possible degradation pathways of OFL and CIP were analyzed based on high resolution mass spectrometry (HRMS) results, moreover, the toxicity evaluation results of Escherichia coli indicated these intermediates products were less toxic compared OFL and CIP. Overall, Bi₂WO₆/Fe₃O₄/BC can provide a potential way for the application of photocatalytic technology in ambient wastewater purification.