Published September 18, 1974
| Version v1
Journal article
Ground electronic state of silylene
Description
Silylene-31Si adds to 1,3-butadiene to give silacyclopent-3-ene-31Si. Studies using nitric oxide as a scavenger demonstrate that the reacting silylene is present as 80 percent triplet and 20 percent singlet, while studies using neon as a moderator prove that the ground electronic state of silylene is a singlet
Additional details
Identifiers
- DOI
- 10.1021/ja00826a002;
Publishing Information
- Journal Title
- Journal of the American Chemical Society
- Journal Volume
- 96
- Journal Issue
- 19
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 5967-5973
- ISSN
- 0002-7863
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 7250919
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CYCLOALKENES; ENERGY LEVELS; HOT ATOM CHEMISTRY; NITROGEN OXIDES; SILANES; SILICON 31
- Descriptors DEC
- ALKENES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHALCOGENIDES; CHEMISTRY; EVEN-ODD NUCLEI; HOURS LIVING RADIOISOTOPES; HYDRIDES; HYDROCARBONS; HYDROGEN COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NITROGEN COMPOUNDS; NUCLEI; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RADIOCHEMISTRY; RADIOISOTOPES; SILICON COMPOUNDS; SILICON ISOTOPES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent