Published January 1988 | Version v1
Journal article Metadata-only

Investigation of ruthenium (3) bromocomplexes interaction with thiourea in solutions

Creators

  • 1. Moskovskij Inst. Tonkoj Khimicheskoj Tekhnologii (USSR)

Description

Interaction of K3(Ru2Br9)(1) and K3(RuBr6)xH2O(2) with thiourea (thio) in HBr solutions is investigated by the methods of absorption and ESR spectroscopy. The (Ru(thio)6)3+ and (Ru(thio)5x(H2O))3+ complexes are shown to be formed in diluted HBr solutions depending on conditions. In the concentrated (7.5 N) HBr solutions interaction of 1 with thio runs through the stage of formation of a binuclear complex with bridge bromide atoms. The rate of formation of thiourea ruthenium (3) complexes is considerably higher for 2 than for 1

Additional details

Additional titles

Original title (Russian)
Исследования взаимодействия бромкомплексов рутения (3) с тиомочевиной в растворах

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
33
Journal Issue
1
Series
Zh. Neorg. Khim.
Journal Page Range
140-143
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
19071363
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; AQUEOUS SOLUTIONS; BROMIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; ELECTRON SPIN RESONANCE; HYDRATES; HYDROBROMIC ACID; POTASSIUM COMPOUNDS; QUANTITY RATIO; REACTION INTERMEDIATES; RUTHENIUM COMPLEXES; THIOUREA
Descriptors DEC
ALKALI METAL COMPOUNDS; ANTITHYROID DRUGS; BROMINE COMPOUNDS; CARBONIC ACID DERIVATIVES; COMPLEXES; DISPERSIONS; DRUGS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; MAGNETIC RESONANCE; MIXTURES; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; REACTION KINETICS; RESONANCE; SOLUTIONS; SPECTRA; SYNTHESIS; THIOUREAS; TRANSITION ELEMENT COMPLEXES