Published December 1985
| Version v1
Journal article
Magnetic susceptibility and specific heat of the one-dimensional conductor (H3O) sub (1,6) Pt (C2O4)2.nH2O at low temperatures
Creators
- 1. Ceara Univ., Fortaleza (Brazil). Instituto de Fisica
- 2. Kernforschungsanlage Juelich G.m.b.H. (Germany, F.R.)
Description
It has been shown recently that some transition metal complexes exhibit one-dimensional metallic properties. It is reported, in this context, susceptibility and specific heat measurements of polycrystalline (H3O)1,6Pt(C2O4)2.nH2O in the low temperature range. It is found that the susceptibility can be described by a non-uniform Curie law with a characteristic break in the slope. The specific heat reveals no linear temperature contribution, which could be explained by a transition into a Peierls distorted state. Until 130K, the heat capacity follows a T3-law. Deviations at higher temperatures are possibly attributed to the anisotropy of the system
Abstract (Portuguese)
Tem sido mostrado recentemente que alguns complexos de metais de transicao apresentam propriedades metalicas unidimensionais. Medidas de susceptibilidade magnetica e calor especifico de (H3O)1,6Pt(C2O4)2.nH2O, um tipico metal unidimensional, a baixas temperaturas, sao estudadas. A susceptibilidade pode ser descrita por uma lei de Curie nao uniforme, com uma troca caracteristica na inclinacao. A baixas temperaturas o calor especifico nao apresenta o termo linear, o que poderia ser explicado por uma transicao para um estado de distorcao de Peierls. Ate 130K, a capacidade calorifica segue a lei T3 e desvios a temperaturas mais altas sao possivelmente atribuidos a anisotropia do sistemaAdditional details
Publishing Information
- Journal Title
- Rev. Bras. Fis.
- Journal Volume
- 5
- Journal Issue
- 3
- Series
- Rev. Bras. Fis.
- Journal Page Range
- 305-314
INIS
- Country of Publication
- Brazil
- Country of Input or Organization
- Brazil
- INIS RN
- 9381264
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- CURIE-WEISS LAW; LOW TEMPERATURE; MAGNETIC SUSCEPTIBILITY; MEDIUM TEMPERATURE; PLATINUM COMPLEXES; SPECIFIC HEAT; ULTRALOW TEMPERATURE; VERY LOW TEMPERATURE
- Descriptors DEC
- COMPLEXES; MAGNETIC PROPERTIES; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES