Subsolidus phase relations in the ZnO-MoO3-B2O3, ZnO-MoO3-WO3 and ZnO-WO3-B2O3 ternary systems
- 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)
- 2. International Center for Materials Physics, Academia Sinica, Shengyang 110016 (China)
- 3. Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100080 (China)
Description
The subsolidus phase relations in the ZnO-MoO3-B2O3, ZnO-MoO3-WO3 and ZnO-WO3-B2O3 ternary systems have been investigated by the means of X-ray powder diffraction (XRD). There is no ternary compound in all the systems. There are five binary compounds and five tie lines in the ZnO-MoO3-B2O3 system. This system can be divided into six 3-phase regions. There are three binary compounds and three tie lines in the ZnO-MoO3-WO3 system. This system can be divided into four 3-phase regions. There are four binary compounds and four tie lines in the ZnO-WO3-B2O3 system. This system can be divided into five 3-phase regions. The possible component regions for ZnO single crystal flux growth were discussed. The phase diagram of Zn3B2O6-ZnWO4 pseudo-binary system has been constructed, and the result reveals this system is eutectic system. The eutectic temperature is 1007 deg. C and eutectic point component is 70 mol% Zn3B2O6
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2007.04.009Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2007.04.009;
- PII
- S0925-8388(07)00815-8;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 458
- Journal Issue
- 1-2
- Journal Page Range
- p. 144-150
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40013186
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- BORON OXIDES; EUTECTICS; MOLYBDENUM OXIDES; MONOCRYSTALS; PHASE DIAGRAMS; TUNGSTEN OXIDES; X-RAY DIFFRACTION; ZINC OXIDES; ZINC TUNGSTATES
- Descriptors DEC
- BORON COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; CRYSTALS; DIAGRAMS; DIFFRACTION; INFORMATION; MOLYBDENUM COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; REFRACTORY METAL COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS; TUNGSTATES; TUNGSTEN COMPOUNDS; ZINC COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.