Oxidation of carbon based material for innovative energy systems (HTR, fusion reactor): status and further needs

Following an overview on kinetics of carbon/gas reactions, status and further needs in selected safety relevant fields of graphite oxidation in high temperature reactors (HTRs) and fusion reactors are outlined. Kinetics was detected due to the presence of such elements as severe air ingress, lack of experimental data on Boudouard reaction and a similar lack of data in the field of advanced oxidation. The development of coatings which protect against oxidation should focus on stability under neutron irradiation and on the general feasibility of coatings on HTR pebble fuel graphite. Oxidation under normal operation of direct cycle HTR requires examinations of gas atmospheres and of catalytic effects. Advanced carbon materials like CFCs and mixed materials should be developed and tested with respect to their oxidation resistance in a common HTR/fusion task. In an interim HTR, fuel storage radiolytic oxidation under normal operation and thermal oxidation in accidents have to be considered. Plans for future work in these fields are described. (authors)