Extraction of scandium by organic substance melts
Creators
- 1. Moskovskij Inst. Stali i Splavov (USSR)
- 2. Kazakhskij Gosudarstvennyj Univ., Alma-Ata (USSR)
Description
Regularities of scandium extraction by the melts of octadecanicoic acid, n-carbonic acids of C17-C20 commerical fraction and mixtures of tributylphosphate (TBP) with paraffin at (70+-1) deg C have been studied. The optimum conditions for scandium extraction in the melt of organic substances are determined. A scheme of the extraction by the melts of higher carbonic acids at ninitial metal concentrations of 10-5 to 10-3 mol/l has been suggested. The scandium compound has been isolated in solid form, its composition having been determined. The main advantages of extraction by melts are as follows: a possibility to attain high distribution coefficients, distinct separation of phases after extraction, the absence of emulsions, elimination of employing inflammable and toxic solvents, a possibility of rapid X-ray fluorescence determinatinon of scandium directly in solid extract
Additional details
Additional titles
- Original title (Russian)
- Экстракция скандия расплавами органических веществ
Publishing Information
- Journal Title
- Zh. Neorg. Khim.
- Journal Volume
- 29
- Journal Issue
- 12
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 3099-3103
- ISSN
- 0044-457X
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 16070225
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL COMPOSITION; DISTRIBUTION FUNCTIONS; MEDIUM TEMPERATURE; MELTING; OCTADECANOIC ACID; PARAFFIN; PH VALUE; QUANTITY RATIO; SCANDIUM CHLORIDES; SCANDIUM COMPLEXES; SOLIDS; SOLVENT EXTRACTION; TBP
- Descriptors DEC
- ALKANES; BUTYL PHOSPHATES; CARBOXYLIC ACIDS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; ESTERS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; OTHER ORGANIC COMPOUNDS; PHASE TRANSFORMATIONS; PHOSPHORIC ACID ESTERS; SCANDIUM COMPOUNDS; SEPARATION PROCESSES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; WAXES
Optional Information
- Notes
- For English translation see the journal Russian Journal of Inorganic Chemistry (UK).