Published December 1984 | Version v1
Journal article

Extraction of scandium by organic substance melts

  • 1. Moskovskij Inst. Stali i Splavov (USSR)
  • 2. Kazakhskij Gosudarstvennyj Univ., Alma-Ata (USSR)

Description

Regularities of scandium extraction by the melts of octadecanicoic acid, n-carbonic acids of C17-C20 commerical fraction and mixtures of tributylphosphate (TBP) with paraffin at (70+-1) deg C have been studied. The optimum conditions for scandium extraction in the melt of organic substances are determined. A scheme of the extraction by the melts of higher carbonic acids at ninitial metal concentrations of 10-5 to 10-3 mol/l has been suggested. The scandium compound has been isolated in solid form, its composition having been determined. The main advantages of extraction by melts are as follows: a possibility to attain high distribution coefficients, distinct separation of phases after extraction, the absence of emulsions, elimination of employing inflammable and toxic solvents, a possibility of rapid X-ray fluorescence determinatinon of scandium directly in solid extract

Additional details

Additional titles

Original title (Russian)
Экстракция скандия расплавами органических веществ

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
29
Journal Issue
12
Series
Zh. Neorg. Khim.
Journal Page Range
3099-3103
ISSN
0044-457X

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).