Published March 1989
| Version v1
Journal article
The first 'lithovanadate': K2[LiVO4]
Description
By heating of well ground mixtures of the binary oxides [K2O, Li2O, V2O5, K:Li:V = 2.2:1.1:1.0; Ni-tube, 900 0C, 46 d] colourless monoclinic single crystals of K2[LiVO4] have been prepared for the first time: space group C2/m; a = 835.7(1) pm, b = 774.5(1) pm, c = 753.3(1) pm, β = 90.23(1)0. The structure was determined by four-circle diffractometer data [MoKα, 1018 from 1262 I0(hkl), R = 8.65%, Rw = 5.67%]. The Madelung Part of Lattice Energy, MAPLE, and Effective Coordination Numbers, ECoN, these via Mean Fictive Ionic Radii, MEFIR, have been calculated. (author)
Additional details
Additional titles
- Original title (German)
- Das erste 'Lithovanadat': K
Publishing Information
- Journal Title
- Zeitschrift fuer Anorganische und Allgemeine Chemie
- Journal Volume
- 570
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 109-118
- ISSN
- 0044-2313
- CODEN
- ZAACA
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 21022817
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ATOMIC RADII; BOND ANGLE; CHEMICAL PREPARATION; COORDINATION NUMBER; COULOMB ENERGY; EXPERIMENTAL DATA; LATTICE PARAMETERS; LITHIUM COMPOUNDS; MONOCLINIC LATTICES; MONOCRYSTALS; POTASSIUM COMPOUNDS; SPACE GROUPS; STRUCTURAL CHEMICAL ANALYSIS; TEMPERING; VANADATES; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DATA; DIFFRACTION; ENERGY; HEAT TREATMENTS; INFORMATION; NUMERICAL DATA; OXYGEN COMPOUNDS; SCATTERING; SYMMETRY GROUPS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS