Measurements of isothermal (vapor + liquid) phase equilibrium for {trifluoroiodomethane (R13I1) + 1,1-difluoroethane (R152a)} from T = (258.150 to 283.150) K
Creators
- 1. Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, P.O. Box 2711, Beijing 100190 (China)
- 2. University of Chinese Academy of Sciences, Beijing 100039 (China)
Description
Highlights: • VLE data for (R13I1 + R152a) system were measured at four temperatures. • Experiments were based on the vapor-recirculation method. • VLE data were correlated using PR−VdWs and PR−HV−NRTL models. • Azeotropic behavior can be found. - Abstract: In this paper, isothermal (vapor + liquid) equilibrium (VLE) values for {trifluoroiodomethane (R13I1) + 1,1-difluoroethane (R152a)} at T = (258.150 to 283.150) K are presented. The experimental apparatus was based on a vapor-recirculation method. The VLE measurements were regressed by the Peng–Robinson equation of state with two models, the Van der Waals mixing rules and the Huron–Vidal mixing rules using the NRTL activity coefficient model. The newly measured VLE values satisfied the thermodynamic consistency test. The results have led to that the two models selected are both suitable for the description of the binary system. Azeotropic behavior can be found for the system measured
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2015.04.011Additional details
Identifiers
- DOI
- 10.1016/j.jct.2015.04.011;
- PII
- S0021-9614(15)00103-2;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 88
- Journal Page Range
- p. 90-95
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 47043188
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- EQUATIONS OF STATE; EQUILIBRIUM; ETHANE; LIQUIDS; METHANE; MIXING; ORGANIC FLUORINE COMPOUNDS; ORGANIC IODINE COMPOUNDS; REACTION KINETICS; TEMPERATURE DEPENDENCE; THERMODYNAMIC ACTIVITY; VAN DER WAALS FORCES; VAPORS
- Descriptors DEC
- ALKANES; EQUATIONS; FLUIDS; GASES; HYDROCARBONS; KINETICS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.