Role of photodetachment in initiation of electric discharges in SF6 and O2

The role of photodetachment in the initiation of electron avalanches near a positive point electrode was investigated for a discharge gap in which the negative ion flux was controlled by UV irradiation of the cathode. For irradiation of the anode region with light beams up to 500 mW, photodetachment was found to make a negligible contribution to avalanche initiation in SF6 and O2 at pressures from 50 to 500 kPA (approx.0.5 to 5 atm). The conditions under which the role of photodetachment might be observed are discussed, and it is shown that for the conditions considered here the expected dominant electron release mechanism in the gap is through collisional detachment of stable negative ions. Previously reported enhancements in avalanche rates resulting from irradiation of a positive point can be explained as arising from increases in negative ion densities due to attachment of photoelectrons ejected by scattered radiation