Published 1985 | Version v1
Journal article Metadata-only

Geometric manifestation of isotope effect and the nature of H-bond in[Et2O...H...OEt2]+ cation of (Et2O)2xHZnCl3 etherate

Creators

  • 1. AN SSSR, Moscow. Inst. Organicheskoj Khimii
  • 2. AN SSSR, Moscow. Inst. Ehlementoorganicheskikh Soedinenij

Description

A 2Et2OxDZnCl3 crystal is studied by the X-ray diffraction method. A zero value of the geometric isotope effect is found, which is indicative of a one-minimum character of an H-bond potential in the [Et2O...H(D)...OEt2]+ cation. Some peculia rity vibrational behaviour of the central H(D) atom is revealed

Additional details

Additional titles

Original title (Russian)
Геометрическое проявление изотопного эффекта и природа Х-связи в катионе [Ет

Publishing Information

Journal Title
Dokl. Akad. Nauk SSSR
Journal Volume
283
Journal Issue
2
Series
Dokl. Akad. Nauk SSSR.
Journal Page Range
395-398
ISSN
0002-3264
CODEN
DANKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
17035029
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CATIONS; CHLORIDES; CRYSTAL STRUCTURE; DEUTERIUM COMPOUNDS; ETHYL ETHER; HYDROGEN COMPOUNDS; ISOTOPE EFFECTS; LATTICE PARAMETERS; LOW TEMPERATURE; MOLECULAR STRUCTURE; MONOCRYSTALS; ZINC COMPLEXES
Descriptors DEC
CHARGED PARTICLES; CHLORINE COMPOUNDS; COMPLEXES; CRYSTALS; ETHERS; HALIDES; HALOGEN COMPOUNDS; IONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS