Published August 22, 2003 | Version v1
Journal article

Theoretical study of excitation-energy transfer in a diarylethyne-linked porphyrin array

Description

Carrying out quantum chemical calculations, we examined the excitation-energy transfer (EET) in a diphenylethyne-linked porphyrin array. The calculations showed that this transfer is caused by nonadiabatic interaction induced by the rotation around the porphyrin-diphenylethyne bond. This result is consistent with our theory that regards, in contrast to Foerster's theory, the EET as a nonadiabatic transition

Additional details

Identifiers

DOI
10.1016/S0040-6090;
PII
S0040609003007600;

Publishing Information

Journal Title
Thin Solid Films
Journal Volume
438-439
Journal Issue
1-2
Journal Page Range
p. 215-220
ISSN
0040-6090
CODEN
THSFAP

Conference

Title
5. international conference on nano-molecular electronics
Dates
10-12 Dec 2002
Place
Kobe (Japan)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
37013500
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
DENSITY FUNCTIONAL METHOD; ENERGY TRANSFER; EXCITATION; INTERACTIONS; PORPHYRINS
Descriptors DEC
CALCULATION METHODS; CARBOXYLIC ACIDS; ENERGY-LEVEL TRANSITIONS; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; VARIATIONAL METHODS

Optional Information

Copyright
Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.