Published April 28, 2004 | Version v1
Journal article Metadata-only

Third-order contributions to the 8S7/2 → 6P7/2, 6P5/2 two-photon transitions of Eu2+ in KMgF3

Creators

  • 1. Structure Research Laboratory, Academica Sinica, Department of Physics, University of Science and Technology of China, Heifei, Anhui 230026 (China)
  • 2. Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR (China)

Description

The line strengths in four polarization directions of the incident radiation of the (8S7/2) →(6P5/2)Γ7, Γ8 and (8S7/2) → (6P7/2)Γ6, Γ7, Γ8 two photon absorption (TPA) transitions of Eu2+ in the perovskite KMgF3 host have been calculated using the third-order Judd-Pooler (JP) formalism. In general, the calculated relative intensities are in good agreement with experiment, except for the ratios between the linear and circular polarizations in the 8S7/2 → 6P7/2 transitions. In particular, the scalar operator term in the third-order spin-orbital correction formula successfully explains nine 8S7/2 → 6P7/2 transitions with different linear polarizations

Availability note (English)

Available online at http://stacks.iop.org/0953-8984/16/2773/cm4_16_002.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/

Additional details

Identifiers

URL
http://stacks.iop.org/0953-8984/16/2773/cm4_16_002.pdf; http://www.iop.org/;
DOI
10.1088/0953-8984/16/16/002;
PII
S0953-8984(04)75089-4;

Publishing Information

Journal Title
Journal of Physics. Condensed Matter
Journal Volume
16
Journal Issue
16
Journal Page Range
p. 2773-2784
ISSN
0953-8984
CODEN
JCOMEL

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
36000523
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S74: ATOMIC AND MOLECULAR PHYSICS; S36: MATERIALS SCIENCE;
Descriptors DEI
ABSORPTION; CALCULATION METHODS; CORRECTIONS; DOPED MATERIALS; ENERGY-LEVEL TRANSITIONS; EUROPIUM ADDITIONS; EUROPIUM IONS; L-S COUPLING; MAGNESIUM FLUORIDES; PEROVSKITE; PHOTONS; POLARIZATION; POTASSIUM FLUORIDES; SPIN
Descriptors DEC
ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; ALLOYS; ANGULAR MOMENTUM; BOSONS; CHARGED PARTICLES; COUPLING; ELEMENTARY PARTICLES; EUROPIUM ALLOYS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INTERMEDIATE COUPLING; IONS; MAGNESIUM COMPOUNDS; MASSLESS PARTICLES; MATERIALS; MINERALS; OXIDE MINERALS; PARTICLE PROPERTIES; PEROVSKITES; POTASSIUM COMPOUNDS; RARE EARTH ADDITIONS; RARE EARTH ALLOYS; SORPTION