Published April 15, 1974
| Version v1
Journal article
Rotational analysis of ν6 of DCF3 and ν3 + ν6 of HCF3
Description
Experimental data of moderately high resolution for the ``pseudoparallel'' bands ν6 of DCF3 and ν3+ν6 of HCF3 are reported. Analysis of ν6 is straightforward and results in values of ν0, α6C and the conclusion that q6>0. ν3+ν6 is perturbed by Fermi resonance with ν5. Analysis in this case yields values of ν0, α3,6C, the anharmonic potential constant |k356| and the conclusion q6>0. The effect of this Fermi resonance on the J = 1←0 pure rotational spectrum of HCF3 is discussed.
Additional details
Identifiers
- DOI
- 10.1063/1.1681507;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 60
- Journal Issue
- 8
- Series
- J. Chem. Phys.
- Journal Page Range
- 3203-3207
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 5151400
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- DEUTERIUM; DEUTERIUM COMPOUNDS; FERMI RESONANCE; FLUOROFORM; INFRARED SPECTRA; ISOTOPE EFFECTS; ROTATIONAL STATES
- Descriptors DEC
- ENERGY LEVELS; EXCITED STATES; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RESONANCE; SPECTRA; STABLE ISOTOPES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent