Published May 1989 | Version v1
Journal article Metadata-only

Spectroscopic investigation of the structure of transition element oxalate complexes wich hydrazine

Creators

  • 1. AN SSSR, Novosibirsk (USSR). Inst. Kataliza
  • 2. AN SSSR, Novosibirsk (USSR). Inst. Neorganicheskoj Khimii

Description

Properties and the structure of genetic series of M(N2H4)2C2O4 compounds, where M = Mn, Fe, Co, Ni, Cu, Zn and Cd are studied by the methods of IR-, ESR and electron spectroscopy of diiffuse reflection. Assignment of bands in absorption spectra is carried out. Metal ions of all complexes investigated are shown to be bound in grids by hydrazine bridge molecules being in equatorial planes, as well as oxalate-ions being in axial positions

Additional details

Additional titles

Original title (Russian)
Спектроскопическое исследование строения комплексов оксалатов переходных металлов с гидразином
Augmented title (English)
Transition elements: Mn, Fe, Co, Ni, Cu, Zn, Cd

Publishing Information

Journal Title
Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk
Journal Issue
no.3
Series
Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk.
ISSN
0002-3426
CODEN
IZSKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21013282
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CADMIUM COMPLEXES; CRYSTAL STRUCTURE; HYDRAZINE; INFRARED SPECTRA; MOLECULAR STRUCTURE; OXALATES
Descriptors DEC
CARBOXYLIC ACID SALTS; COMPLEXES; SPECTRA